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61.
Geochemistry of oceanic carbonatites compared with continental carbonatites: mantle recycling of oceanic crustal carbonate 总被引:11,自引:2,他引:11
Kaj Hoernle George Tilton Mike J. Le Bas Svend Duggen Dieter Garbe-Schönberg 《Contributions to Mineralogy and Petrology》2002,142(5):520-542
Major and trace element and Sr-Nd-Pb-O-C isotopic compositions are presented for carbonatites from the Cape Verde (Brava, Fogo, Sáo Tiago, Maio and Sáo Vicente) and Canary (Fuerteventura) Islands. Carbonatites show pronounced enrichment in Ba, Th, REE, Sr and Pb in comparison to most silicate volcanic rocks and relative depletion in Ti, Zr, Hf, K and Rb. Calcio (calcitic)-carbonatites have primary (mantle-like) stable isotopic compositions and radiogenic isotopic compositions similar to HIMU-type ocean island basalts. Cape Verde carbonatites, however, have more radiogenic Pb isotope ratios (e.g. 206Pb/204Pb=19.3-20.4) than reported for silicate volcanic rocks from these islands (18.7-19.9; Gerlach et al. 1988; Kokfelt 1998). We interpret calcio-carbonatites to be derived from the melting of recycled carbonated oceanic crust (eclogite) with a recycling age of ~1.6 Ga. Because of the degree of recrystallization, replacement of calcite by secondary dolomite and elevated 13C and 18O, the major and trace element compositions of the magnesio (dolomitic)-carbonatites are likely to reflect secondary processes. Compared with Cape Verde calcio-carbonatites, the less radiogenic Nd and Pb isotopic ratios and the negative Ɨ/4 of the magnesio-carbonatites (also observed in silicate volcanic rocks from the Canary and Cape Verde Islands) cannot be explained through secondary processes or through the assimilation of Cape Verde crust. These isotopic characteristics require the involvement of a mantle component that has thus far only been found in the Smoky Butte lamproites from Montana, which are believed to be derived from subcontinental lithospheric sources. Continental carbonatites show much greater variation in radiogenic isotopic composition than oceanic carbonatites, requiring a HIMU-like component similar to that observed in the oceanic carbonatites and enriched components. We interpret the enriched components to be Phanerozoic through Proterozoic marine carbonate (e.g. limestone) recycled through shallow, subcontinental-lithospheric-mantle and deep, lower-mantle sources. 相似文献
62.
This paper is the first in a two-part series that discusses the principal axes of M-DOF structures subjected to static and dynamic loads. The primary purpose of this series is to understand the magnitude of the dynamic response of structures to enable better design of structures and control modification devices/systems. Under idealized design conditions, the structural responses are obtained by using single direction input ground motions in the direction of the intended control devices/systems,and by assuming that the responses of the structure is decoupleable in three mutually perpendicular directions. This standard practice has been applied to both new and retrofitted structures using various seismic protective systems. Very limited information is available on the effects of neglecting the impact of directional couplings (cross effects - of which torsion is a component) of the dynamic response of structures. In order to quantify such effects, it is necessary to examine the principal axes of structures under both static and dynamic loading.This first paper deals with quantitative definitions of principal axes and "cross effects" of three-dimensional structures under static load by using linear algebra. It shows theoretically that, for three-dimensional structures, such principal axes rarely exist. Under static loading conditions, the cross effect is typically small and negligible from the viewpoint of engineering applications. However, it provides the theoretical base for subsequent quantification of the response couplings under dynamic loads, which is reported in part Ⅱ of this series. 相似文献
63.
Two end-member types of pyroclastic density current are commonly recognized: pyroclastic surges are dilute currents in which particles are carried in turbulent suspension and pyroclastic flows are highly concentrated flows. We provide scaling relations that unify these end-members and derive a segregation mechanism into basal concentrated flow and overriding dilute cloud based on the Stokes number (ST), the stability factor (ΣT) and the dense-dilute condition (DD). We recognize five types of particle behaviors within a fluid eddy as a function of ST and ΣT: (1) particles sediment from the eddy, (2) particles are preferentially settled out during the downward motion of the eddy, but can be carried during its upward motion, (3) particles concentrate on the periphery of the eddy, (4) particles settling can be delayed or ‘fast-tracked’ as a function of the eddy spatial distribution, and (5) particles remain homogeneously distributed within the eddy. We extend these concepts to a fully turbulent flow by using a prototype of kinetic energy distribution within a full eddy spectrum and demonstrate that the presence of different particle sizes leads to the density stratification of the current. This stratification may favor particle interactions in the basal part of the flow and DD determines whether the flow is dense or dilute. Using only intrinsic characteristics of the current, our model explains the discontinuous features between pyroclastic flows and surges while conserving the concept of a continuous spectrum of density currents. 相似文献
64.
A critical state interpretation for the cyclic liquefaction resistance of silty sands 总被引:1,自引:0,他引:1
George D. Bouckovalas Konstantinos I. Andrianopoulos Achilleas G. Papadimitriou 《Soil Dynamics and Earthquake Engineering》2003,23(2):115-125
Contrary to many laboratory investigations, common empirical correlations from in situ tests consider that the increase in the percentage of fines leads to an increase of the cyclic liquefaction resistance of sands. This paper draws upon the integrated Critical State Soil Mechanics framework in order to study this seemingly not univocal effect. Firstly the effect of fines on the Critical State Line (CSL) is studied through a statistical analysis of a large data set of published monotonic triaxial tests. The results show that increasing the content of non-plastic fines practically leads to a clockwise rotation of the CSL in (e–ln p) space. The implication of this effect on cyclic liquefaction resistance is subsequently evaluated with the aid of a properly calibrated critical state elasto-plastic constitutive model, as well as a large number of published experimental results and in situ empirical correlations. Both sets of data show clearly that a fines content, less than about 30% by weight, may prove beneficial at relatively small effective stresses (p0<50–70 kPa), such as the in situ stresses prevailing in most liquefaction case studies, and detrimental at larger confining stresses, i.e. the stresses usually considered in laboratory tests. To the extent of these findings, a correction factor is proposed for the practical evaluation of liquefaction resistance in terms of the fines content and the mean effective confining stress. 相似文献
65.
George F. Risk T. Grant Caldwell Hugh M. Bibby 《Journal of Volcanology and Geothermal Research》2003,127(1-2):33-54
Experimental measurements in the Ngatamariki geothermal field, North Island, New Zealand were made to test the applicability of the time domain electromagnetic method for detailed investigation of the resistivity structure within a geothermal field. Low-frequency square wave signals were transmitted through three grounded bipole current sources sited about 8 km from the measurement lines. Despite high levels of electrical noise, transient electric field vectors could be determined reliably for times between 0.02 and 3.3 s after each step in the source current. Instantaneous apparent resistivity tensors were then calculated. Apparent resistivity pseudosections along the two measurement lines show smooth variations of resistivity from site to site. Over most of the field the images consistently show a three-layer resistivity structure with a conductive middle layer (3–10 Ωm) representing the conductive upper part of the thermal reservoir. A deep-seated region of low resistivity in the northwest of the field may indicate a conductive structure at about 1 km associated with a deeper diorite intrusion. Measurements sited closer than about 100 m to drillholes appear to have been disturbed by metallic casing in the holes. A change in resistivity structure in the east of the field may indicate a major geological or hydrothermal boundary. 相似文献
66.
67.
68.
Iron and Sulfur Chemistry in a Stratified Lake: Evidence for Iron-Rich Sulfide Complexes 总被引:5,自引:1,他引:5
George W. Luther III Brian Glazer Shufen Ma Robert Trouwborst Bradley R. Shultz Gregory Druschel Charoenwan Kraiya 《Aquatic Geochemistry》2003,9(2):87-110
A four month study of a man-made lake used for hydroelectric power generation in northeastern Pennsylvania USA was conducted
to investigate seasonal anoxia and the effects of sulfide species being transported downstream of the power generation equipment.
Water column analyses show that the system is iron-rich compared to sulfide. Total Fe(II) concentrations in the hypolimnion
are typically at least twice the total sulfide levels. In situ voltammetric analyses show that free Fe(II) as [Fe(H2O)6]2+ or free H2S as H2S/HS- are either not present or at trace levels and that iron-rich sulfide complexes are present. From the in situ data and total Fe(II) and H2S measurements, we infer that these iron-rich sulfide complexes may have stoichiometries such as Fe2SH3+ (or polymeric forms of this and other stoichiometries). These iron-rich sulfide complexes appear related to dissolution of
the iron-rich FeS mineral, mackinawite, because IAP calculations on data from discrete bottle samples obtained from bottom
waters are similar to the pKsp of mackinawite. Soluble iron-sulfide species are stable in the absence of O2 (both in lake waters and the pipeline) and transported several miles during power generation. However, iron-sulfide complexes
can react with O2 to oxidize sulfide and can also dissociate releasing volatile H2S when the waters containing them are exposed to the atmosphere downstream of the powerplant. Sediment analyses show that
the lake is rich in oxidized iron solids (both crystalline and amorphous). Fe concentrations in FeS solids are low (<5 μmole/grdry wt) and the pyrite concentration ranges from about equal to the solid FeS to 30 times the solid FeS concentration. The degree
of pyritization is below 0.12 indicating that pyrite formation is limited by free sulfide, which can react with the iron-rich
sulfide complexes. 相似文献
69.
Given the difficulty of separating the three Picea species—P. glauca, P. mariana, and P. rubens (white, black, and red spruce)—in the pollen record, little is known about their unique histories in eastern North America following deglaciation. Here we report the first use of a classification tree analysis (CART) to distinguish pollen grains of these species. It was successfully applied to fossil pollen from eight sites in Maine and one in Massachusetts. We focused on the late glacial/early Holocene (14,000 to 8000 cal yr B.P.) and the late Holocene (1400 cal yr B.P. to present)—the two key periods since deglaciation when Picea has been abundant in the region. The result shows a shift from a Picea forest of P. glauca and P. mariana in the late glacial to a forest of P. rubens and P. mariana in the late Holocene. The small number of P. rubens grains identified from the late glacial/early Holocene samples (<5%) suggests that that species was either absent or rare at most of the sites. The occurrence and distribution of the three species do not reveal any geographic or temporal trend during late glacial time, but the data suggest that they were distributed in local patches on the landscape. The results of this study indicate that the recent population expansion of Picea (1000 to 500 cal yr B.P.) was likely the first time since deglaciation that P. rubens was abundant in the region. 相似文献
70.
Gregory K. Druschel Robert J. Hamers George W. Luther III Jillian F. Banfield 《Aquatic Geochemistry》2003,9(2):145-164
The oxidation kinetics of trithionate (S3O62-
) and tetrathionate (S4O
6
2-
) with hydroxyl radicals (OH*) have been investigated in systems analogous to acid mine drainage (AMD) environments. The discovery of hydroxyl radical
(OH*) formation on pyrite surfaces (Borda et al., 2003) suggests hydroxyl radicals may affect the oxidation kinetics of intermediate
sulfur species such as tetrathionate. Cyclic voltammetry experiments in acidic solutions indicate that the reaction of S4O
6
2-
with OH* goes through an unknown intermediate, tentatively assigned as S3O
4
n-
. An outer-sphere electron transfer mechanism for the reaction of S4O
6
2-
with OH* to form S3O
4
n-
is proposed based on experimental results. Oxidation rates for trithionate and tetrathionate in the presence of Fenton's
reagent (which forms hydroxyl radicals) are too fast to be directly measured using UV-Vis spectrophotometry, electrochemical,
or stop-flow spectrophotometry methods. Competitive reaction kinetics within the context of the Haber—Weiss mechanism suggests
that the rate constant for the oxidation of trithionate and tetrathionate with OH* is in excess of 108 M-1 sec-1. 相似文献